Even if gaming is unimportant to you I'd still recommend the PS3. It's a fantastic media machine (with video upscaling, audio upsampling, streaming capabilities, etc.), with new features being added with every consecutive upgrade.
For me the only benefit of the Oppo would be DVD-Audio playback but I have very few DVD-A discs (as opposed to quite a few SACDs). The only other thing I could think of is its 'AV component' design i.e. it fits in a stack, against PS3 obvious console design